

The magnesite ore dissociates in the combustion zone, producing highly reactive, ultra fine particles of MgO which are effective in controlling and often reducing slag formation in the furnace. Hence, boiler operations are improved and are manifest as increased heat transfer and improved efficiency (lower furnace exit gas temperatures), extended run time between outages and reduced maintenance and repairs. Another major benefit, particularly with higher sulfur coals, is the reduction of detrimental emissions of sulfur trioxide (SO3). This reduction is often greater than 50% when CoalTreat™-500 is applied at the proper dosage level. Lower SO3 is beneficial in reducing metal corrosion in the boiler cool zone and improves plume opacity/visible emissions (VE’s).
The fine particles of MgO from CoalTreat™-500, which have a high surface area, will also adsorb mercury vapor as they pass through the unit. While it is not possible to predict removal rates, it is reasonable to expect a relatively high removal, based on the large number of additional particles added to the gas stream.
EPA data show that many power plants are already experiencing some mercury removal as a co-benefit of existing air pollution control systems. EPRI is evaluating sorbent injection in front of a particulate collector. One of the preferred sorbents is activated carbon, a very expensive and difficult to handle material which also negatively impacts the quality (sale-ability) of flyash.
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